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mu-Chloro-mu-methylenebis(cyclopentadienyl)titaniumdimethylaluminum, 0.5M in toluene, Each

185.39

Details

mu;-Chloro-μ-methylenebis(cyclopentadienyl)titaniumdimethylaluminum is used in organic synthesis for carbonyl methylenation, A versatile methylenation reagent for the conversion of ketones and aldehydes to olefins, it offers facile reaction with hindered ketones and allows the conversion of esters to vinyl ethers. Tebbe reagent can be used to olefinate aldehydes, to methylenate a chiral polyhydroxyketone with high diasteroselctivity.

Additional Information

SKU 10023170
UOM Each
UNSPSC 12161500
Manufacturer Part Number 044506AA
CAS Number 67719-69-1
Is Hazardous Yes
HS Code 2931009900
UN Number UN 2924
Proper Shipping Name TEBBE REAGENT
Packaging Group PG II
Hazardous Class 4.3
Label
Molecular Formula C13H4AlClTi
EC Number Unspecified
Hazard Statement H261-H302-H318-H333-H361-H225-H304-H314-H336-H361d-H373
Precautionary Statements P223-P301+P310a-P303+P361+P353-P405-P501a-P210-P261-P280-P301+P310-P305+P351+P338-P310
Risk Statements 11-34-48/20-63-65-67
GHS GHS02,GHS05,GHS07,GHS08
GHS (Pictogram)
Safety Statements 26-36/37/39-45-62-16
Hazard Code F,C
Signal Word Danger