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Specifications CAS Number: 96-33-3Formula: C4H6O2Formula Weight: 86.09Linear Formula: CH2=CHCOOCH3MDL No.: MFCD00008627Purity: 0.99Boiling Point: 80 C(lit.)Melting Point: -75 C (lit.)Density: 0.956 g/mL at 25 C(lit.)Refractive Index: n20/D 1.402(lit.)Storage: 2-8CBeilstein Registry Number: 605396EC Number: 202-500-6UNSPSC Code: 12162002General description: Methyl acrylate is an acrylic monomer. It is useful in the preparation of polymers having rigid, flexible, ionic, nonionic, hydrophobic, or hydrophilic properties. Mechanism of the copolymerization of ethylene and α-olefins with methyl acrylate has been studied. Heck reaction of iodobenzene with methyl acrylate in the presence of triethylamine and sodium carbonate has been reported. The reversible addition fragmentation chain transfer (RAFT) bulk polymerization of methyl acrylate using 1-phenylethyl dithiobenzoate and 2-(2-cyanopropyl) dithiobenzoate (RAFT agents) has been studied. Reactive intermediates formed during the Heck reaction of methyl acrylate have been characterized by NMR spectroscopy.Application: Methyl acrylate was used in the preparation of poly(methyl acrylate) elastomers. It was also used in the synthesis of α,ω-dicarboxylic acid esters.RTECS: AT2800000RIDADR: UN 1919 3 / PGIIWGK Germany: 2Flash Point(F): 26.6 FFlash Point(C): -3 CR Codes: 11-20/21/22-36/37/38-43S Codes: 9-25-26-33-36/37-43IOD Codes: F,XnSymbol: GHS02, GHS06Signal Word: DangerHazard Statements: H225-H302 H312-H315-H317-H319-H331-H335-H412Precautionary statements: P210-P261-P273-P280-P305 P351 P338-P311
