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Specifications CAS Number: 100-58-3Formula: C6H5BrMgFormula Weight: 181.31Linear Formula: C6H5MgBrMDL No.: MFCD00000038Density: 1.134 g/mL at 25 CBeilstein Registry Number: 3588849UNSPSC Code: 12352103General description: Phenylmagnesium bromide solution contains 3M phenylmagnesium bromide in diethyl ether. It can act as a strong acid and Lewis acid. It can undergo addition reaction with many unsaturated functional groups. The phenyl group can displace halide from other organic compounds. Phenylmagnesium bromide is a Grignard reagent. Reaction of β-cyclohexanedione (dihydroresorcinol) with phenylmagnesium bromide has been investigated.Application: Phenylmagnesium bromide was used for the synthesis of end-functionalized regioregular poly(3-alkylthiophene)s. It was also used for the monoalkylation of aliphatic primary amine to generate secondary amines by the Grignard reaction of 1-[(alkylamino) methyl] benzotriazoles. It may be used for synthesis of the following: . 1,3,3-trimethyl-6-phenyl-2-oxabicyclo[2.2.2]octan-6-ol. 6-benzyl-1,3,3-trimethyl-2-oxabicyclo[2.2.2]octan-6-ol . (3-(2-Dithiobenzoatepropionyl)propyl)dimethylmethoxysilane, reversible addition-fragmentation chain transfer polymerization (RAFT)-silane agent . series of o-substituted benzophenonesOther Notes: Storage below 25C may cause formation of crystalline magnesium salts. Moving container to a warm location and occasional gentle swirling should redissolve the solidRIDADR: UN 2924 8(3) / PGIIWGK Germany: 3Flash Point(F): -40 FFlash Point(C): -40 CR Codes: 11-14-19-22-34-67S Codes: 9-16-26-33-36/37/39-45IOD Codes: F,CSymbol: GHS02, GHS05, GHS07Signal Word: DangerHazard Statements: H225-H314-H336Precautionary statements: P210-P260-P280-P305 P351 P338-P370 P378-P403 P235
